PC (Polycarbonate) CNC Machining Material Manual
PC (Polycarbonate / Lexan / Makrolon) — CNC Machining Material Manual
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Rating legend — ★★★★★ best · ★☆☆☆☆ worst. For machinability/wear/heat resistance more stars = better; for cost, fewer stars = cheaper.
📋 Material Quick-Reference Card
┌──────────────────────────────────────────────┐
│ Material Name: Polycarbonate (PC) │
│ (Lexan / Makrolon / transparent PC) │
│ Category: Amorphous engineering plastic │
│ (transparent impact-resistant resin)│
│ Density: 1.20~1.22 g/cm³ │
│ Tensile Strength: 60~70 MPa │
│ Flexural Strength: 90~100 MPa │
│ Hardness: Rockwell M70~M75 / R118 │
│ Heat Deflection Temp.: 130~140 ℃ │
│ Machinability: ★★★★☆ (good, heat-sensitive) │
│ Impact Resistance: ★★★★★ (virtually unbreak.) │
│ Chemical Resistance: ★★☆☆☆ │
│ Cost: ★★★★☆ (higher than PMMA/ABS) │
│ Keywords: transparent, tough, impact-resistant│
│ safety shield, electrical insulation│
└──────────────────────────────────────────────┘
1. Material Overview
1.1 Introduction
PC (Polycarbonate) is a transparent, tough, high-impact engineering plastic widely used when a part must combine optical visibility with mechanical safety. It is much tougher than PMMA (acrylic) and is often described as virtually unbreakable in guard, shield, and protective-window applications.
- English Name: Polycarbonate / PC
- Common Nicknames: Transparent PC, engineering PC, bullet-resistant plastic (application-dependent)
- Famous Brand Names: Lexan (SABIC), Makrolon (Covestro), Panlite
1.2 Two Main Types ⭐ Important
| Type | Full Name | Characteristics |
|---|---|---|
| Clear / Optical PC | Transparent polycarbonate sheet/rod | High impact strength with approx. 88~90% light transmission; used for covers, windows, guards |
| Flame-Retardant PC | FR PC, UL94 V-0 / V-2 grades | Improved flame performance and electrical safety; common for electrical housings and insulators ⭐ Common for CNC |
| Glass-Filled PC | GF-PC, usually 10~30% glass fiber | Higher stiffness, lower creep, better dimensional stability; less transparent and more abrasive to tools |
💡 Clear PC is selected when visibility + safety are required. FR PC is selected for electrical and equipment parts where flame rating matters. Glass-filled PC is selected when stiffness is more important than transparency.
1.3 Raw Material Forms
Common forms for CNC machining:
- PC Rod (round bar): turned transparent parts, spacers, insulators
- PC Sheet/Plate: milled windows, covers, guards, enclosures
- Common colors: clear, smoke/tinted, black, natural translucent, custom colors
2. Composition & Physical Properties
2.1 Material Composition
PC is an amorphous thermoplastic polymer containing carbonate groups in its molecular chain. Its amorphous structure gives it transparency, good dimensional stability, and no true crystalline melting point. Commercial PC is commonly produced from bisphenol-A polycarbonate resin, with additives used for UV resistance, flame retardancy, color, or glass-fiber reinforcement.
| Type | Molecular Structure |
|---|---|
| Standard PC | Amorphous polycarbonate resin with carbonate linkages, transparent and tough |
| FR PC | PC resin with flame-retardant additive package for UL94 V-0 / V-2 grades |
| Glass-Filled PC | PC resin reinforced with glass fiber for stiffness and creep resistance |
2.2 Physical Properties
| Property | Value |
|---|---|
| Density | 1.20~1.22 g/cm³ |
| Melting Point | No true melting point (amorphous); softening range approx. 145~155 ℃ |
| Heat Deflection Temp. | 130~140 ℃ |
| Long-term Service Temp. | -40 |
| Thermal Conductivity | 0.19~0.22 W/(m·K) |
| Water Absorption | 0.15~0.35% (moderate-low) |
| Coefficient of Thermal Expansion | 65~70×10⁻⁶ /℃ |
| Light Transmission | Approx. 88~90% (clear grades) |
💡 PC offers good dimensional stability and low shrinkage for an amorphous plastic, but it absorbs some moisture. For precision machining or optical work, dry stock and avoid sudden temperature changes.
3. Mechanical & Chemical Properties
3.1 Mechanical Properties
| Property | Value |
|---|---|
| Tensile Strength | 60~70 MPa |
| Flexural Strength | 90~100 MPa |
| Elastic Modulus | 2200~2400 MPa |
| Elongation | 80~120% (grade-dependent) |
| Hardness | Rockwell M70~M75 / R118 |
| Impact Strength | Extremely high; virtually unbreakable in many practical uses |
| Coefficient of Friction | 0.35~0.45 (not self-lubricating) |
⚠️ PC has far higher impact resistance than PMMA, ABS, and many other transparent plastics. However, it scratches more easily than PMMA and often needs hard coating for optical covers.
3.2 Chemical Resistance
| Medium | Resistance |
|---|---|
| Water, neutral salts | ✅ Good |
| Dilute acids | ✅ Fair to good |
| Oils, greases | ⚠️ Generally fair, verify grade compatibility |
| Alcohols | ⚠️ Limited; stress cracking possible |
| Alkalis | ❌ Poor, especially strong alkalis |
| Ketones, aromatic solvents, chlorinated solvents | ❌ Poor; swelling, crazing, stress cracking |
| UV light (long-term outdoor) | ⚠️ Fair, requires UV-stabilized or coated grades |
3.3 Notable Characteristics
- Extreme impact strength: the first choice for transparent safety shields and protective windows
- Transparent + tough: approx. 88~90% light transmission with much higher toughness than PMMA
- Good heat resistance: continuous service commonly around 115~130 ℃ depending on grade/load
- Good electrical insulation: widely used for electrical covers, insulators, and housings
- Naturally flame-retardant tendency: many grades burn less readily than common plastics; FR grades can meet UL94 V-0 / V-2
4. CNC Machining Process ⭐⭐ Core
4.1 Machinability Rating
★★★★☆ Good machinability, but heat-sensitive and stress-sensitive — PC can be CNC machined accurately, but it requires more process control than POM or PMMA:
- Sharp polished tools are essential; dull tools cause heat, melting, and cloudy edges
- Chips can become gummy if heat is not removed quickly
- Transparent parts show scratches, tool marks, and stress whitening easily
- Drilled and tapped holes are prone to cracking or crazing if internal stress is not relieved
4.2 Recommended Tooling
| Item | Recommendation |
|---|---|
| Tool Material | Sharp carbide preferred; polished HSS acceptable for some drilling/turning |
| Cutting Edge | Very sharp, polished edge to reduce friction and gumming |
| Rake Angle | Positive rake angle (10°~20°) |
| Helix Angle | High helix for chip evacuation and low cutting pressure |
| Flutes | 1 |
4.3 Recommended Cutting Parameters
| Operation | Spindle Speed (RPM) | Feed Rate (mm/min) | Depth of Cut (mm) |
|---|---|---|---|
| Rough Milling | 8000~16000 | 800~2500 | 0.5~3 |
| Finish Milling | 10000~20000 | 300~1200 | 0.1~0.5 |
| Turning | 1000~3000 | 0.05~0.25/rev | 0.2~1.5 |
| Drilling | 1000~4000 | 30~150 | — |
📌 Parameters are for reference only; adjust based on machine rigidity, tool diameter, grade, wall thickness, and whether the part is optical/transparent.
4.4 Machining Challenges & Solutions
| Challenge | Cause | Solution |
|---|---|---|
| Melting / gumming | Cutting heat, dull tools, poor chip evacuation | Use sharp polished tools, high RPM with moderate feed, air blast, peck cycles |
| Stress cracking / crazing | Residual stress in stock; aggressive coolant/solvents; tight drilled/tapped holes | Anneal before machining and before/after drilling/threading; avoid solvent coolants; use proper hole clearance |
| Cloudy or scratched surface | Tool rubbing, chips recutting, poor handling | Use climb finishing passes, air evacuation, protective film, clean soft fixtures |
| Drill grabbing or exit cracking | High thrust and heat at hole exit | Use plastic drill geometry, backing support, peck drilling, reduced feed near breakthrough |
| Dimensional drift after machining | Internal stress release and moisture/temperature change | Rough machine → anneal → finish machine; store dry; stabilize temperature before inspection |
4.5 Annealing Recommendation ⭐
To reduce cracking, crazing, and dimensional movement, annealing is strongly recommended for precision PC parts and especially for drilled/tapped transparent parts:
Reference Annealing Process:
• Temperature: 120~125 ℃
• Time: approx. 30~60 min per 25mm of wall thickness
• Cooling: slow furnace cooling to below 60 ℃ before removal
💡 For PC, the safest workflow is dry stock if needed → rough machining → annealing → finish machining → optional final annealing. This is especially important around holes, threads, sharp inside corners, and solvent-exposed parts.
4.6 Cooling Methods
- Air blast: preferred for most PC machining; removes chips without introducing chemical stress cracking
- Dry cutting: acceptable when tools are sharp and chip evacuation is excellent
- Water-soluble coolant: use only PC-compatible fluids; test before production
- ❌ Avoid aggressive cutting fluids, alcohols, ketones, chlorinated solvents, and alkaline cleaners
5. Surface Treatment
PC supports more finishing options than POM, but transparent parts require careful handling because scratches and stress marks are visible:
| Process | Feasibility | Notes |
|---|---|---|
| Polishing | ✅ Good | Mechanical polishing can improve clarity; avoid overheating and stress whitening |
| Vapor polishing | ✅ Feasible | Can improve transparent edges; requires controlled process and ventilation |
| Hard coating | ✅ Common | Improves scratch and chemical resistance for windows, guards, and covers |
| Painting | ✅ Feasible | Better paintability than POM/PTFE; surface cleaning and primer improve adhesion |
| Bonding / adhesives | ✅ Good | Bonds with compatible solvent cements, epoxies, acrylic adhesives; avoid stress cracking |
| Laser marking | ✅ Feasible | Works well on filled/colored grades; clear grades may need additives or coating |
| Dyeing / tinting | ⚠️ Limited | Usually supplied as tinted sheet/rod; post-dyeing is less common |
💡 If a transparent part needs scratch resistance, specify hard-coated PC. If the top priority is optical clarity and scratch resistance with low impact load, choose PMMA instead.
6. Applications & Material Selection
6.1 Typical Application Industries
| Industry | Application Parts |
|---|---|
| Machine safety | Machine guards, safety shields, impact-resistant viewing windows |
| Industrial equipment | Transparent covers, protective enclosures, inspection windows |
| Lighting | Light covers, lenses, LED diffusers, protective lamp housings |
| Electrical / electronics | Insulators, terminal covers, FR housings, equipment panels |
| Medical and lab equipment | Transparent covers, fixtures, trays, protective lab parts |
| Automotive / transport | Interior covers, protective lenses, impact-resistant trim parts |
| Precision components | Impact-resistant machined parts, spacers, structural transparent parts |
6.2 Pros & Cons Summary
| ✅ Advantages | ❌ Disadvantages |
|---|---|
| Extremely high impact strength; much tougher than PMMA | Lower scratch resistance than PMMA; often needs hard coating |
| Transparent with approx. 88~90% light transmission | Lower optical clarity than PMMA |
| Good heat resistance for a transparent plastic | Poor resistance to many solvents and alkalis |
| Good dimensional stability and electrical insulation | Prone to stress cracking around holes/threads if not annealed |
| Paintable, bondable, hard-coatable, vapor-polishable | More expensive than PMMA and ABS |
| FR grades available; naturally flame-retardant tendency | Gummy and heat-sensitive during machining |
6.3 Material Selection Guide
✔ Recommended for PC:
- Transparent guards, covers, and windows requiring high impact resistance
- Parts where PMMA is too brittle or unsafe under impact
- Electrical insulators and FR-grade housings requiring good dielectric performance
- Medical, lab, and machine components needing toughness + visibility
- Impact-resistant precision machined parts with moderate heat exposure
✘ Not recommended for:
- Best optical clarity and scratch resistance → choose PMMA
- Strong solvent, alkali, or chemical exposure → choose PTFE, PVDF, or suitable chemical-resistant plastic
- Low-cost non-transparent housings → choose ABS
- High-wear sliding parts → choose POM or nylon
- High temperature (>130℃ continuous) → choose PEEK, PPS, or PI
⚠️ Safety & Handling Notes
| Hazard | Detail | Precaution |
|---|---|---|
| Combustible dust | Fine PC chips/dust can be combustible and may irritate airways | Use dust extraction; avoid dust accumulation and ignition sources |
| Fume generation | Overheating from dull tools can produce irritating fumes | Keep tools sharp, control heat, ensure ventilation/extraction |
| Solvent stress cracking | Many solvents, cutting fluids, alcohols, and alkaline cleaners can cause crazing/cracks | Avoid aggressive fluids; test coolant/cleaner compatibility before use |
| Surface scratching | Clear PC scratches easily during clamping, deburring, and cleaning | Keep protective film on as long as possible; use soft jaws and clean gloves |
| Storage | PC absorbs some moisture and can mark or warp if stored poorly | Store dry, flat, indoors, away from UV and heat sources |
⚠️ Never assume a coolant or cleaner is safe for PC. Even if the part looks fine after machining, residual stress plus incompatible chemicals can cause delayed crazing or cracking around holes, threads, and sharp corners.
🔗 Related Pages
- Plastic Materials Handbook (overview)
- PMMA (Acrylic) — clearer and more scratch-resistant, but much more brittle
- ABS — lower-cost, paintable plastic for non-transparent housings